Practice Test: Question Set - 22
1. For an ideal gas, the activity co-efficient is
- (A) Directly proportional to pressure
- (B) Inversely proportional to pressure
- (C) Unity at all pressures
- (D) None of these
2. As the time is passing, entropy of the universe
- (A) Is increasing
- (B) Is decreasing
- (C) Remain constant
- (D) Data insufficient, can't be predicted
3. In the equation, PVn = constant, if the value of n = ± ∞, then it represents a reversible __________ process.
- (A) Adiabatic
- (B) Isometric
- (C) Isentropic
- (D) Isothermal
4. The acentric factor of a materical, 'ω', is defined as ω = -log10(Prsat)Tr-1 = 0.7, where, Prsat = reduced vapor pressure, Tr = reduced temperature. The value of acentric factor is always
- (A) > 2
- (B) < 1
- (C) > 1
- (D) < 3
5. Which of the following is not an intensive property?
- (A) Volume
- (B) Density
- (C) Temperature
- (D) Pressure
6. "If different processes are used to bring about the same chemical reaction, the enthalpy change is same for all of them". This is __________ law.
- (A) Hess's
- (B) Kirchoff's
- (C) Lavoisier and Laplace
- (D) None of these
7. Steam undergoes isentropic expansion in a turbine from 5000 kPa and 400°C (entropy = 6.65 kJ/kg K) to 150 kPa) (entropy of saturated liquid = 1.4336 kJ/kg. K, entropy of saturated vapor = 7.2234 kJ/kg. K) The exit condition of steam is
- (A) Superheated vapor
- (B) Partially condensed vapor with quality of 0.9
- (C) Saturated vapor
- (D) Partially condensed vapor with quality of 0.1
8. A gas can be liquefied by pressure alone only, when its temperature is __________ its critical temperature.
- (A) Less than
- (B) More than
- (C) Equal to or higher than
- (D) Less than or equal to
9. The expression, ∆G = nRT. ln(P2/P1), gives the free energy change
- (A) With pressure changes at constant temperature
- (B) Under reversible isothermal volume change
- (C) During heating of an ideal gas
- (D) During cooling of an ideal gas
10. Heat is added at constant temperature in an ideal __________ cycle.
- (A) Stirling
- (B) Brayton
- (C) Rankine
- (D) None of these
11. What is the degree of freedom for two miscible (non-reacting) substances in vapor-liquid equilibrium forming an azeotrope?
- (A) 0
- (B) 1
- (C) 2
- (D) 3
12. Heat evolved/absorbed during conversion of a substance from one allotropic form to another is termed as the heat of
- (A) Fusion
- (B) Vaporization
- (C) Transition
- (D) None of these
13. For any system, what is the minimum number of degrees of freedom?
- (A) 0
- (B) 1
- (C) 2
- (D) 3
14. Solubility of a substance which dissolves with an increase in volume and liberation of heat will be favored by the
- (A) Low pressure and high temperature
- (B) Low pressure and low temperature
- (C) High pressure and low temperature
- (D) High pressure and high temperature
15. At the critical point of a substance
- (A) The surface tension vanishes
- (B) Liquid and vapor have the same density
- (C) There is no distinction between liquid and vapor phases
- (D) All (a), (b) and (c)
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