Practice Test: Question Set - 12
1. Rate of an autocatalytic chemical reaction is a function of
- (A) Temperature only
- (B) Pressure only
- (C) Composition only
- (D) All (a), (b) and (c)
2. Time required for 50% decomposition of a liquid in an isothermal batch reactor following first order kinetics is 2 minutes. The time required for 75% decomposition will be about __________ minutes.
- (A) 3
- (B) 4
- (C) 6
- (D) 10
3. The reactions with low activation energy are
- (A) Always spontaneous
- (B) Slow
- (C) Fast
- (D) Non-spontaneous
4. The concentration of A in a first order reaction, A → B, decreases
- (A) Linearly with time
- (B) Exponentially with time
- (C) Very abruptly towards the end of the reaction
- (D) Logarithmically with time
5. A reaction which is catalyzed by an acid is also catalyzed by any substance, which has a tendency to
- (A) Lose a proton
- (B) Gain a proton
- (C) Lose an electron
- (D) None of these
6. 'n' number of plug flow reactors (P.F.R) in series with a total volume 'V' gives the same conversion as one P.F.R. of volume
- (A) V/n
- (B) V
- (C) V.n
- (D) 1/V
7. Chemical kinetics can predict the __________ of a chemical reaction.
- (A) Rate
- (B) Feasibility
- (C) Both (a) & (b)
- (D) Neither (a) nor (b)
8. Pick out the correct statement.
- (A) A catalyst speeds up the forward reaction but slows shown the
reverse reaction
- (B) Addition of catalyst changes the equilibrium constant
- (C) Pressure changes do not change the equilibrium concentrations
- (D) The composition of equilibrium is changed by catalyst
9. The reaction in which the rate equation corresponds to a stoichiometric equation, is called a/an __________ reaction.
- (A) Elementary
- (B) Non-elementary
- (C) Parallel
- (D) Autokinetic
10. Half life period of a chemical reaction is proportional to CA0-1, if the reaction is of __________ order.
- (A) First
- (B) Zero
- (C) Second
- (D) Third
11. Reaction rate of a first order reaction, which is half completed in 23 minutes will be
- (A) 0.03 sec-1
- (B) 0.03 min-1
- (C) 0.03 hr-1
- (D) 0.05 min-1
12. B.E.T. method of finding out surface area of a catalyst, uses the extension of __________ isotherm.
- (A) Langmuir
- (B) Freundlich
- (C) Tempkin
- (D) None of these
13. A typical example of an exothermic reversible reaction conducted at high pressure in industry is
- (A) Dehydration of ethanol
- (B) Methanol synthesis
- (C) Reformation of methane
- (D) Polymerization of ethylene
14. Vegetable oils are hydrogenated in a __________ reactor.
- (A) Slurry
- (B) Plug flow
- (C) Homogeneous catalytic
- (D) None of these
15. Pick out the wrong statement.
- (A) Autocatalytic reactions are exemplified by microbial fermentation
reactions
- (B) The slowest step has the greatest influence on the overall reaction
rate in case of an irreversible series reaction
- (C) The fractional conversion at any time is same for both the constant
as well as the variable volume system in case of an irreversible unimolecular
type first order reaction
- (D) Hydrolysis of ester in presence of alkali or acid is a zero order
reaction
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