Practice Test: Question Set - 34
1. The rate of forward reaction, at chemical equilibrium is _________the rate of backward reaction.
- (A) More than
- (B) Less than
- (C) Equal to
- (D) Either (b) or (c)
2. The rate constant of a first order reaction depends on the
- (A) Concentration of the reactant
- (B) Temperature
- (C) Concentration of the product
- (D) Time
3. An exothermic reaction takes place in an adiabatic reactor. The product temperature __________ reactor feed temperature.
- (A) Is always equal to
- (B) Is always greater than
- (C) Is always less than
- (D) May be greater or less than
4. The units of frequency factor in Arrhenius equation
- (A) Are the same as those of the rate constant
- (B) Depend on the order of the reaction
- (C) Depend on temperature, pressure etc. of the reaction
- (D) Are cycles per unit time
5. Which of the following is the most suitable for isothermal operation?
- (A) Batch reactor
- (B) Back-mix reactor
- (C) Plug-flow reactor
- (D) Fixed bed reactor
6. Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is:
- (A) 0
- (B) 1
- (C) 2
- (D) 3
7. The rate at which a chemical substance reacts is proportional to its
- (A) Active mass
- (B) Molecular weight
- (C) Equivalent weight
- (D) Atomic weight
8. A catalyst in a chemical reaction __________ free energy change in the reaction.
- (A) Increases
- (B) Decreases
- (C) Either (a) or (b); depends on the type of catalyst
- (D) Neither (a) nor (b)
9. Sum of the powers of the concentration terms in the rate equation is called the __________ of the reaction.
- (A) Order
- (B) Overall order
- (C) Molecularity
- (D) None of these
10. The ratio of volume of mixed reactor to the volume of P.F.R. (for identical flow rate, feed composition and conversion) for zero order reaction is:
- (A) ∞
- (B) 0
- (C) 1
- (D) > 1
11. Thermodynamic equilibrium constant in a system is affected by
- (A) Inerts
- (B) Pressure
- (C) Temperature
- (D) All (a), (b) & (c)
12. In case of __________ reactions, the reaction rate does not decrease appreciably as the reaction proceeds.
- (A) Catalytic
- (B) Parallel
- (C) Series
- (D) Auto catalytic
13. Considering the endothermic dissociation of CaCO3 in a closed vessel (CaCO3 ⇌ CaO + CO2), the pressure of CO2 increases, if
- (A) A catalyst is added
- (B) The temperature is increased
- (C) An inert gas is pumped keeping the temperature constant
- (D) None of these
14. The catalytic activity of enzymes is due to their capacity to lower the __________ energy.
- (A) Activation
- (B) Potential
- (C) Kinetic
- (D) None of these
15. Carrier in a catalyst increases its
- (A) Surface area
- (B) Activity
- (C) Performance
- (D) None of these
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